Please use this identifier to cite or link to this item: http://archive.cmb.ac.lk:8080/xmlui/handle/70130/6911
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dc.contributor.authorMUNASIRI, BHARDRA-
dc.date.accessioned2022-09-30T03:19:47Z-
dc.date.available2022-09-30T03:19:47Z-
dc.date.issued1973-
dc.identifier.urihttp://archive.cmb.ac.lk:8080/xmlui/handle/70130/6911-
dc.description.abstractA summary of the kinet ics of chemical and electro-chemical reactions are discussed. lhe next Chapter on Discussion and Interpretation of results allows our method of analysis of the i/t transients. elcccroer; stallisation transient is estimated froiu the observed transient. Different models i.ere examined and a c^est fitting rjodcl is derived for the i/1 variation in this taaAsient. The importance of epecific adsorption of chloride ions in electrocrystallisation is t&oiei from a calculation of char.-jo*transfer resistance. Our present studies on the anodic electrocrystallisation of calomel on mercury show that the Devanuthan aaacxni saouex iu ccrreci. The experimental technique used in the measurement of the i/t transient is detailed in the next Chapter* Results arc obtained a modified electrode for txj transients for five different concentrations of HC1 and I iC10/, namely 0.4u SCI, l.Oia IIC1, 0.1/» HC1 + 4 0.9’1 IIC10, , and x.tl4 HU10, . 4 4 In the fourth Chapter, the techniques available for stud/iny. the kinetics of fast reactions are shown in detail. The u>asic equation for the current due to electrochemical reactions are ^iven. -he work done by various schools of research in this field, is summarised in the fifth Chapter. The present state of knowledge of the electrocr/s tallisation of calomel is discussed here. In the next Chapter, the concepts of electrocrystailisation and factors that govern nucleation and growth are sum-harised. An intixxluction to the types of anodic electrocrysta— llisation reactions are then . dven. The theories that have Lcen developed for the stud; of electrocheaical reactions are discussed.en_US
dc.language.isoenen_US
dc.publisherFaculty of Science, University of Colomboen_US
dc.titleKineiies of electrocrystailisation of calonel in chloride solutions under Potentionstatic conditionsen_US
dc.typeThesisen_US
Appears in Collections:MPhil/PhD theses

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